An Overview Of Hazardous Chemicals

ials that are extremely hazardous to property, healthengineering controls and a special permit from the
or the environment (highly toxic gas, explosive, highlySeattle Fire Department.
water reactive, and pyrophoric materials for example)Incompatible Materials: Incompatible materials are
must not be procured until the necessary permits,materials which, when in contact with each other,
administrative, engineering and environmental controlshave the potential to react in a manner that
are in place.generate heat, fumes, gases, or byproducts which
Hazardous materials must be stored and used inare hazardous. For quantities of greater than 5
accordance with numerous regulations including, butpounds or 1/2 gallon, separation by not less than 20
not limited to, the Uniform Fire Code and localfeet, approved cabinets, or a noncombustible
amendments.partition is required. Smaller quantities should also be
Permits are required for any quantity of highlyisolated whenever practical. A common violation is
hazardous material, and for small to moderateflammable liquids stored with oxidizers.
quantities of other materials. (For example, a permit isFlammable Liquids and Basements: The International
required for any quantity of highly toxic or unstableFire Code prohibits storage of flammable liquids in
material and for flammable liquids in quantities inbasements. However, there are two general
excess of five gallons in a building).exceptions as follows that apply to the University of
Contact the Fire Department directly or EH&SWashington:
Facility Safety office (206.543.0465) for assistance.Existing grandfathered Class H Occupancy rooms (i.e.,
Rooms where hazardous materials are stored orchemical stockrooms design specifically for bulk
used in quantities that exceed certain thresholds, andstorage of flammable liquids). New Class H occupancy
rooms dedicated to storing hazardous materials arerooms for flammable liquids are not allowed in
required to have a National Fire Protection Associationbasements.
(NFPA) diamond sign on all doors. Call EH&SYour waste will be picked up in two to four weeks.
Facility Safety office at 543-0465 for furtherPlease plan ahead and be patient. Each waste item
information and signs.must be tracked from the point of generation to
Flammable Liquids: The quantity of flammable liquids inincineration, and we do the paperwork for hundreds
a single laboratory stored outside of an approvedof containers of waste every week. Chemicals that
flammable liquids cabinet must not exceed 10 gallons.are corrosive, flammable, toxic, or explosive are by
All 10 gallons, unless in use, must be stored inlegal definition "hazardous". Some additional chemicals
approved containers as indicated in the table below.are handled as hazardous waste because they are
Peroxide Forming Chemicals: Peroxides may form incarcinogenic, persistent in the environment, or are
some organic compounds by autoxidation. Peroxidesnot allowed in the trash because they generate dusts
can cause serious accidents and, in someor other hazard. Large volumes of waste or numbers
circumstances, become low power explosives thatof containers may take longer to collect due to the
can be set off by shock, sparks or other forms oflong time it takes to process the chemicals (it usually
ignition. Some organic compounds form peroxides in atakes an hour to process one Chemical Collection
matter of months under the right circumstance. BeRequest) and the limited space on our trucks. Routine
aware of organic compounds in your lab andcollection requests are faster because much of the
remember to mark the expiration date on eachpaperwork is done already. If your waste is
container and review them periodically for disposal.accumulated improperly (according the above
Ether is an example of peroxide forming chemical.guidelines), we will stop to discuss the problem with
Pyrophoric Material: Pyrophoric material is a materialyou if you are present. We will not pick up your
that will spontaneously ignite when it comes intowaste until the problem has been corrected.
contact with air. This material is only permitted in fireAll new employees as well as anyone rusty on the
sprinkler protected laboratories in very small quantitiesbasics of hazardous waste management should take
(4 pounds aggregate per zone). Potassium metal is anthis training. It covers hazardous waste definitions,
example of a pyrophoric material. Extreme precautionlabeling, storage, and disposal and includes a short
is required when working with this type of material.quiz, all of which should take only ten to twenty
Highly Toxic Material: Materials classified as highly toxicminutes to complete. If you pass the quiz, you may
are only permitted in small quantities in Universityrequest a certificate of completion for your training
buildings (Up to 10 pounds per zone). Highly toxic gas,records at any job that you are working at.
like Arsine, is not allowed in any quantity without